非晶Fe73.5Cu1Nb3Si13.5B9合金激光纳米化的超精细结构研究

在CO₂激光功率为50—300W、扫描速度为20mm/s、激光散光斑为20mm照射条件下 ，诱导非 晶Fe_735Cu₁Nb₃Si_135B9带中发生结构重组，产生定量纳米α-F e(Si)晶相形成双相组织结构材料. 利用穆斯堡尔谱研究了非晶Fe_735C u₁Nb₃Si_135B₉合金激光纳米化的 超精细结构. 实验结果表明，激光诱导非晶 Fe_735Cu₁Nb₃Si_135B ₉纳米化后，其超精细磁场的分布随 着激光功率变 化由单峰向双峰变化，在高功率辐照时， 出现了双峰分布，并且峰位向高场移动. 高激光 功率辐照非晶Fe_735Cu₁Nb₃Si_{135B9合金纳米晶化相有四种超精细结 构，即2个超精细磁场较小的初晶相和2个超精细磁场较大的纳米晶化相. 其中超精细磁场较 大(17—25MA/m)的α-Fe(Si)相为DO3结构. 关键词： 激光 纳米晶α-Fe（Si) 735}Cu₁Nb< sub>3Si_135B₉')" href="#">非晶Fe_735Cu₁Nb< sub>3Si_135B₉ 超精细结构 超精细磁场     

PdCu alloy nanoclusters: generation and activity tuning for electrocatalytic oxidation of nitrite

The process control of electrodeposition of nanoparticles by cyclic voltammetry (CV) is important with respect to the preparation of highly active catalysts. We have simultaneously deposited novel nanoclusters of PdCu alloys on the surface of glassy carbon electrodes (GCEs) from a solution. SEM, XPS, XRD and electrochemical techniques were used for characterizing the nanocomposite and the modified electrode (PdCu/GCE). We found that the PdCu alloys form liana-like fractal 2D-nanoclusters on the base and spherical 3D-nanoclusters on the top, and these clusters consisted of 9.9 nm average sized nanoparticles. The 2D-clusters have strong ability to reduce the overpotentials of nitrite oxidation but have small influence on the current response. Inversely, the 3D-clusters have weak ability to influence the overpotentials but strong ability to influence the current response. It is found that the cycle number is important to the catalytic activity of the generated nanoclusters and 25 cycle number was the optimal for obtaining most negative peak potential (0.77 V vs. SCE) with highest CV peak current (0.53 A/M · cm²) and DPV peak current for nitrite oxidation. This PdCu/GCE can be used as a sensitive and stable nitrite sensor with wide linear range. Mechanisms of the deposition and catalytic activity of the nanoclusters are discussed.     

冲击加载下LY12铝合金的动态屈服强度和层裂强度与温度的相关性

采用可测量任意反射表面的速度干涉仪对LY12铝合金在不同初始温度条件下的动态屈服与层裂行为进行了实验研究，温度范围从室温到接近熔化温度.实验结果显示：LY12铝合金的动态屈服强度随着温度升高而快速下降，当初始温度为847K (比熔化温度低86K) 时，其屈服强度仅为室温下的15％，层裂强度也随着温度升高而减小，在296—847K的实验温度范围内，层裂强度损失80%.通过实验结果与模型估算值的比较，发现Zerilli-Armstrong (ZA) 模型可以对LY12铝合金的动态屈服强度与温度的相关性进行较好 关键词： 温度相关性 LY12铝合金 动态屈服强度 层裂强度     

高压Ni77P23非晶合金自由体积变化的同步辐射研究

利用同步辐射高能X光散射的方法，研究了室温下非晶合金Ni₇₇P₂₃的自由体积的变化所引起的压缩行为的变化规律，通过傅里叶变换得到不同压力下的径向分布函数，并由此获得了不同压力下，该非晶合金的配位数、近邻原子间距等原子构型的结构信息. 研究表明，至直30.5GPa压力，Ni₇₇P₂₃合金仍保持稳定的非晶结构,根据Bridgman方程通过拟合数据，得到状态方程为-ΔV/V₀=0.08606P-3.2×10^-4P²+5.7×10^-6P³. 关键词： 非晶合金 自由体积 同步辐射     

铁基非晶稀土合金的结构转变和结构弛豫

通过对铁基非晶稀土合金结构转变和结构弛豫过程特征的研究，讨论了该材料的稳定性；认为稀土成份是影响合金品质和应用前景的关键因素。     

Fluctuation‐assisted crystallization of an iPP/PEOc polymer alloy prepared on a single multicatalyst reactor granule

The new fluctuation‐assisted mechanism for nucleation and crystallization in the isotactic polypropylene/poly(ethylene‐co‐octene) alloy has been studied. We found that the liquid–liquid phase separation (LLPS) had a dominant influence on the crystallization kinetics through the nucleation process. After LLPS, the nucleation of crystallization mainly occurred at the interface of the phase‐separated domains. It is because that the concentration fluctuations of the LLPS induced the motion of polymer chains and possibly some segmental alignment and/or orientation in the concentration gradient regions through interdiffusion, which could assist the formation of nuclei for crystallization. In other words, the usual nucleation energy barrier could be overcome (or at least partially) by the concentration fluctuation growth of LLPS in the unstable regions. This could be viewed as a new kind of heterogeneous nucleation and could be an addition to the regular nucleation and growth mechanism for crystallization. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 166–172, 2009     

茜素紫分光光度法测定锌合金中的微量锡

在酸度0.15N、波长570nm处,消除干扰元素的情况下,利用葛素紫与锡形成稳定紫红色赘合物,用分光光度计测定锌合金中的微量锡。经比对实验证明,该方法准确可靠。     

Al-Cu多晶锯齿形屈服现象中的尺度效应

对Al-Cu多晶合金锯齿形屈服现象中各特征物理量(应力跌幅、跌落时间和再加载时间)随应变演化的规律进行了系统研究，讨论了不同厚度试件演化结果的区别.同时，这种尺度效应还表现为相同加载条件下1，2mm厚度试件与3mm厚度试件的Portevin-Le Chrtelier (PLC)类型的差异.利用非线性时间序列分析的方法对前者在相空间中吸引子的几何特性进行了描述，并通过主分量分析的方法初步判定其中存在着混沌行为.后者演化过程中应力跌落事件按跌落幅度统计分布符合幂律规律，具有自组织临界性特征.最后，借助自组织 关键词： 锯齿形屈服 尺度效应 Al-Cu合金